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The Mechanism of Enamine Formation. The overall equation for enamine formation from cyclohexanone a ketone and pyrrolidine a 2? Writing a mechanism for this reaction provides a good test of ones' understanding of acid-catalyzed processes.

OH Br-Br. Side Reactions during the Enamine Formation. Enamines from Imines. Enamines from Alkenes, Alkynes and Allenes. Enamines by the Horner-Wittig Reaction. If you can understand why the two reactions of imine and enamine formation are essentially identical, and can write a detailed mechanism for each one, you are well on the way to mastering organic chemistry.

Problem Enamines act as Michael donors in conjugate addition reactions Section Draw the structure of the product formed by reaction of the enamine of cyclohexanone and pyrrolidine with methyl vinyl ketone. A second alkylation of the C2 alkylated intermediate with various bromoalkanes yielded 2,2-disubstituted products, which upon treatment with TFA, provided access to trisubstituted furans.

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